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Journal and Proceedings of
The Royal Society of New South Wales

Volume 132 Parts 1 and 2 [Issued June 1999]

CONTENTS

AUTHORS & TITLES PAGES
O'Connor, D.J. The Australian Republic and the Royal Society of New South Wales. [Presidential Address, 1999] 1-10
Baker, N.J., Xiao, L.H., Craig D.C. & Baker A.T. Metal Complexes of Linear Sexadentate Ligands: Dwyer and Lions Revisited 11-22
Organ, Michael "...a small fish in a small pond....". The Reverend W.B. Clarke (1798-1878): 200 Years On (Part II) 23-28
Laurie J. Lawrence, Vera Munro-Smith, Anthony R. Ramsden, James L. Sharpe & Peter A. Williams Geology and Mineralogy of the Lorena Gold Mine, Cloncurry District, North-west Queensland 29-35
Theses Abstracts
[Not available on this page, but available in full here]
John R Burgess The Pathogenesis and Behaviour of Clinical Endocrinopathy in Multiple Endocrine Neoplasia Type 1 37
Monica Anne Hamilton-Bruce Conventional and Topographic Electroencephalography and Somatosensory Evoked Potential Studies in Ischaemic Stroke 38
Anthony H. Harakuwe Capillary Zone Electrophoresis: Studies on Separation Selectivity of Inorganic Anions 39-40
Helen Monks The Management of Regional Economic Development Organisations with a Particular Emphasis on Funder Relationships 41
Firoozeh Rabbani A Study Of The Scaling Behavior Of Some Cr2O3 Forming Alloys With Relevance To Inter-connect Plates For Solid Oxide Fuel Cells 43-44
Seán Stewart Thermodynamic and Dielectric Properties in Modulated Two-dimensional Electronic Systems 45-46
Christina Wright "Where The Spirits Meet" A History of The National Museum And Art Gallery, Waigani, Papua New Guinea 47-48

vol 132 parts 1-2 pp. 1-10

The Australian Republic and the Royal Society of New South Wales

[Presidential Address, 1999]

D.J. O'Connor

No Abstract Return to Top

vol 132 pts 1-2, pp. 11-22

Metal Complexes of Linear Sexadentate Ligands: Dwyer and Lions Revisited

N.J. Baker, L.H. Xiao, D.C. Craig & A.T. Baker

ABSTRACT: The linear sexadentate ligands 1,8-bis(salicylideneamino)-3,6-dithiaoctane (H2L1) and 1,8-bis(2-pyridylmethyleneamino)-3,6-dithiaoctane (L2) have been prepared and a number of metal complexes have been isolated. The ligands have been characterised by nmr spectroscopy and mass spectrometry. The metal complexes have been characterised by electrospray mass spectrometry, electronic spectroscopy, microanalyses and magnetic susceptibility measurements. Three complexes have been structurally characterised by x-ray diffractometry (all triclinic, space group P1, Z 2): [NiL2][ClO4]2 a 9.963(4), b 10.953(5), c 13.145(5)Å, α 103.43(2), β 96.75(2) γ 116.06(2)°, R 0.038 for 3193 observed reflections; [FeL2][ClO4]2 a 9.771(4), b 10.783(5), c 13.126(5)Å, α 104.07(2), β 96.81(3) γ 114.91(2)°, R 0.039 for 2364 observed reflections and {[CuHL1][ClO4]}2.CH3CN.0.5H2O a 11.762(7), b 13.647(8), c 16.207(10)Å, α 82.41(4), β 79.98(4) γ 76.79(5)°, R 0.060 for 3977 observed reflections.

Keywords: sexadentate ligands, metal complexes, crystal structures.

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vol 132 pts 1-2, pp. 23-28.

"...a small fish in a small pond....". The Reverend W.B. Clarke (1798-1878): 200 Years On (Part II)

Michael Organ

Abstract: See Vol. 131 pts 3-4, p101.

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vol 132 pts 1-2, pp. 29-35.

Geology and Mineralogy of the Lorena Gold Mine, Cloncurry District, North-west Queensland

Laurie J. Lawrence, Vera Munro-Smith, Anthony R. Ramsden, James L. Sharpe & Peter A. Williams

Abstract. The Lorena gold deposit, near Cloncurry, northwest Queensland, contains an unusual Au-Bi-As-Cu-Co assemblage. Gold is intimately associated with native bismuth and bismuthinite, and the Co is confined to solid solution in arsenopyrite. Analyses of the primary phases and mineral associations point to a hydrothermal origin for the deposit. Secondary cobalt species include cobaltian conichalcite, heterogenite-2H, cobaltian calcite and abundant wupatkiite, the cobalt member of the halotrichite group. The major secondary enriched copper sulfide in the deposit is the rare species, geerite.

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